Portable energy storage technology

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A self-powered system based on energy harvesting technology can be a potential candidate for solving the problem of supplying power to electronic devices. In this review, we focus on portable and wearable self-powered systems, starting with typical energy harvesting technology, and introduce portable and wearable self-powered systems with sensing functions. In addition, we demonstrate the potential of self-powered systems in actuation functions and the development of self-powered systems toward intelligent functions under the support of information processing and artificial intelligence technologies.

In recent years, portable and wearable electronic devices have been in a stage of rapid development1,2. Personalized electronic devices such as smart watches and smart glasses have sprung up, bringing much convenience to people''s life3,4. At the same time, with the promotion of flexible electronic technology5, big data technology6,7 and artificial intelligence technology8, portable and wearable electronic devices have shown the development trend of flexibility, integration, and intellectualization, which have also facilitated rich applications such as health monitoring9,10, human–machine interaction11,12, and the Internet of Things13,14.

For portable and wearable electronic devices, the energy supply is a major obstacle to its flexible and integrated application. Replaceable batteries are now the common energy source of electronic devices. However, the rigid characteristics of these batteries limit the overall flexibility of electronic devices. The limited life of batteries and potential environmental pollution problems also do not conform to the principles of sustainable development. As a result, many efforts have been made to explore new environmentally friendly, renewable energy sources to power electronic devices.

Self-powered technology provides a solution for the sustainable energy supply of portable and wearable systems. Self-powered technology means that the device can maintain its own operation by collecting energy in the working environment without an external energy supply. The effective collection of various forms of energy in the working environment is the basis of self-powered technology.

Electronic devices such as actuators can assist humans in completing diverse and complex operations in specific scenarios. The development of self-powered technology makes it possible to realize various actuation functions without an external energy supply. For example, many researchers use electrical energy converted from other forms of energy as an excitation signal to realize the functions of automatic control41,42, microfluidics43,44, drug delivery and release45, and adjuvant therapy46,47.

From a long-term point of view, we will eventually witness human society entering the age of intelligence. The Internet of Things, artificial intelligence, and big data technology change our lives with each passing day. The relationship between human beings and electronic devices has also presented an unprecedented state. Electronic devices with a single function will no longer meet the functional requirements of portable electronic devices in the intelligent era. Portable and wearable self-powered intelligent systems are gradually replacing bulky computers as the interface of a new generation of intelligent human–machine interactions and playing an important role in intelligent identification48, intelligent control49, and other fields.

Energy harvesting is the basis of a self-powered system. Additionally, for consideration of convenience and environmental protection, we need sustainable, clean, and renewable energy to power portable and wearable devices. There are various forms of energy in the environment, including not only the energy produced by the human body itself but also the energy provided by the external environment. In daily life, human mechanical movements such as finger movement, walking, and running can produce considerable mechanical energy. However, due to the multimode and low-frequency characteristics of human mechanical movement, it is not easy to collect the mechanical energy of the human body effectively.

Triboelectric and piezoelectric generators are the two most common ways to collect mechanical energy generated by human motion. Triboelectric energy harvesting is based on the well-known principle of friction electrification. The contact of two different objects will induce static charges on the surface of the objects. Subsequently, the relative motion between the two charged objects will produce a potential difference, thus driving the flow of charges. Due to the advantages of a wide selection of materials, low operating frequency and high output power, TENGs have become the most common ways of collecting the mechanical energy of human motion.

In Fig. 1a, an arch-shaped TENG was proposed by Z. L. Wang''s research group in 201254. The pyramid patterns on the surface of the TENG help increase the output of the TENG by increasing the contact area of the two triboelectric layers. The output voltage, current density, and energy volume density of the TENG reached 230 V, 15.5 μA cm−2 and 128 mW cm−3, respectively. The energy conversion efficiency is as high as 10–39% and meets the demands of wireless sensor systems and mobile phones. This work demonstrates for the first time the potential of TENGs for driving personal mobile electronic devices and shows how TENGs can affect lifestyle.

a Arch-shaped TENG as a power supply for mobile phones. Reprinted from ref. 54 with permission. b Hybrid nanocomposite generator (hNCG) for hand movement energy harvesting. Reprinted from ref. 68 with permission. c Flexible thermoelectric generator (f-TEG) for harvesting human thermal energy. Reprinted from ref. 73 with permission. d Wearable textile-based hybrid supercapacitor–biofuel cell (SC–BFC) system as a biochemical energy harvester. Reprinted from ref. 77 with permission.

Since invented by Wang in 2012, TENGs have been studied systematically in materials55,56, structure57,58, working mode59,60,61,62, and power management63,64, during which time, the output of TENGs has been greatly improved. As the most suitable energy harvesting method for human motion mechanical energy, TENGs still face some shortcomings that need to be overcome. For example, stability and reliability are the largest problems. The ability of reliable power management and tolerance to environmental factors such as humidity and temperature also need to be further studied.

Jeong et al. developed a 1D–3D (1–3) fully piezoelectric nanocomposite using perovskite BaTiO3 (BT) nanowire-employed poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) for a high-performance hybrid nanocomposite generator (hNCG) device (Fig. 1b). The output of the flexible hNCG reached 14 V and 4 μA when used for hand movement energy harvesting. Such output performance is higher than the current levels of even previous piezoceramic film-based flexible energy harvesters68.

In addition to collecting hand movement energy, piezoelectric energy harvesters also play important roles in intelligent shoes69, implantable devices70, and intelligent fabrics71 for biomechanical energy harvesting. Compared with TENGs, piezoelectric energy harvesters may be limited by the range of material selection. However, the advantages of a higher output current, simple structure, and working mode still make piezoelectric generators an indispensable method for mechanical energy harvesting.

In addition to the mechanical energy produced by human motion, the heat energy of the human body is also valuable energy that can be collected and utilized. The body temperature is constant, and there is a temperature difference with the external environment. Therefore, the use of a thermoelectric generator can achieve continuous energy harvesting. The working principle of a thermoelectric generator is based on the Seebeck effect, that is, the diffusion of electrons and holes caused by a temperature gradient.

There have been many studies on flexible thermoelectric generators (f-TEG) using inorganic thin-film thermoelectric materials or organic compound materials72. However, the energy conversion efficiency of these thermoelectric generators is too low to meet the power demand of portable and wearable electronic devices.

The human body is a complex physiological environment. In addition to biomechanical energy and heat energy, the human body also has available chemical energy. Biofuel cells are an energy harvesting technology that can collect chemical energy from the human body. Biofuel cells are mainly divided into enzyme-catalyzed biofuel cells and microbial cell catalytic fuel cells that use biofuels such as ethanol74 or glucose75 to realize the conversion of chemical energy to electric energy.

In the current research, the output power density of biofuel cells is approximately a few microwatts per square centimeter. This level of energy output makes the biofuel cell insufficient to supply sufficient energy in any actual scenario76.

Therefore, Lv et al. integrated biofuel cells into self-charging units and presented a wearable textile-based hybrid supercapacitor–biofuel cell (SC–BFC) system (Fig. 1d)77. This kind of biofuel cell can scavenge biochemical energy from human sweat and store it in a supercapacitor module. A hybrid energy system integrated with an energy harvesting and energy storage module can solve the problem of the small output energy of biofuel cells and ensure a stable energy supply.

On the basis of single energy harvesting technology, a hybrid energy harvesting system integrated with multiple modes takes advantage of various energy harvesting methods and improves the energy efficiency. For example, biomechanical energy can only be collected when the human body maintains a specific motion posture, while the thermoelectric generator can continuously harvest energy regardless of the human state.

In Fig. 2a, Lee et al. fabricated a highly stretchable, hybrid energy-scavenging nanogenerator based on a micropatterned piezoelectric P(VDF-TrFE) polymer, a micropatterned polydimethylsiloxane (PDMS)–carbon nanotube composite and graphene nanosheets78. The P(VDF-TrFE) polymer has both a piezoelectric effect and excellent thermoelectric properties with pyroelectric coefficients up to ≈200 µCm−2 K−1. This kind of hybrid energy harvester can realize the simultaneous collection of biomechanical energy and heat energy when attached to a human hand, a shoulder, an elbow, and other parts.

a Piezoelectric and thermoelectric hybrid energy-scavenging nanogenerator. Reprinted from ref. 78 with permission. b Solar-triboelectric hybrid energy harvesting system. Reprinted from ref. 79 with permission. c Hybrid energy harvester based on triboelectric and electromagnetic principles. Reprinted from ref. 80 with permission.

As a kind of sustainable clean energy, solar energy plays an important role in the field of energy harvesting. The simultaneous collection of solar energy and biomechanical energy is also regarded as an effective means to improve energy collection efficiency. H. X. Zhang''s group proposed a solar-triboelectric hybrid energy harvesting system (Fig. 2b)79. Through the design of a common electrode structure and the introduction of an energy management module, this kind of hybrid energy harvester achieves a better charging effect than a single energy harvesting mode in the charging test of capacitors.

In addition, this research group has also proposed a hybrid energy harvester based on triboelectric and electromagnetic principles (Fig. 2c)80. Compared with TENGs, electromagnetic generators are different in principle, output characteristics, and applicable frequency. Therefore, integration can achieve complementary advantages to adapt to a variety of applications. In this work, a flexible hybrid energy harvester is proposed based on magnetic and conductive PDMS material, which complements the large output voltage characteristics of TENGs and the large output current characteristics of electromagnetic generators. This hybrid energy harvester can charge a capacitance of 10 μf to 3 V in 110 s, which is superior to the TENG or EMG only.

Energy harvesting technology is the basis of self-powered systems, giving these systems the ability to achieve some functions without an external energy supply. As a necessary way for electronic devices to perceive the external environment, sensors are the cornerstone of the rich functions of electronic devices. Sensors used in wearable scenes can also act as an extension of five human sense organs, giving humans stronger environmental perception capabilities. Therefore, self-powered systems have great application potential in the wearable sensing field.

On the basis of energy harvesting technology, a variety of portable, wearable self-powered sensors for monitoring physical, chemical, and physiological information have been developed. There are two main ways to realize self-powered sensing. The first is active sensing, which uses the electrical signal itself as the sensing signal, where the output electrical signal will be affected by some external factors. Active sensing has been widely used in the monitoring of pressure81, humidity82, and temperature83.

In Fig. 3a, Liu et al. reported self-powered epidermal electronics with a tactile sensing function84. This kind of epidermal electronics can reflect the pressure on the skin, as well as the pressure distribution, through the triboelectric signal, which is of broad potential interest in wearable electronics.

The output of the piezoelectric material will be affected by its deformation degree, which allows these materials to realize the active sensing of human body postures.

Yang et al. showed a flexible wearable pressure sensor based on piezoelectric materials (Fig. 3b)85. On the basis of organic/inorganic piezoelectric material BaTiO3(BTO)/polyvinylidene fluoride(PVDF) composites, polydopamine was introduced as a surface modifier to modify BTO, bringing the improved dispersion of BTO in the organic PVDF matrix. The pressure sensor can realize the active sensing of the elbow bending posture when placed on the elbow of the human body.

In addition, a new self-powered strain sensor based on redox electricity has been proposed using a graphene/Ecoflex film and meandering zinc wire (Fig. 3c)86. In the state of stretching, the resistance of graphene/Ecoflex increases with increasing strain, which leads to a decrease in the redox current. This sensor has been utilized to realize the active motion detection of knee joints.

However, pressure sensors based on triboelectric or posture sensors based on piezoelectric and redox electricity are only small-scale laboratory devices as the primary prototype. To achieve a stable wearable active sensor that can cover the whole body of the human body, it is also necessary to solve key problems such as weak device stability and a single sensing mode.

In Fig. 3d, Shen et al. developed an active humidity sensor based on a moisture-driven electrical generator, which realizes the sensing of another physical quantity in addition to the common pressure and strain87. The output voltage of the generator is strongly dependent on the humidity of the ambient environment. This new type of device can play the role of self-powered wearable human breathing monitors and touch pads.

In addition to active sensing, using an energy harvester as an energy supply, driving the sensor module is another way to realize wearable self-powered sensing. This mode is mainly used for monitoring physiological indexes of the human body, such as glucose, urea, NH4+, and pH.

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